Catalytic Addition of Indole-2-Carboxylic Acid to 1-Hexyne
نویسندگان
چکیده
منابع مشابه
Formation of indole-3-carboxylic acid by Chromobacterium violaceum.
l-Tryptophan is converted to indole-3-carboxylic acid by growing cultures and resting cell suspensions of Chromobacterium violaceum
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Model systems are critical to our understanding of self-assembly processes. As such, we have studied the surface self-assembly of a small and simple molecule, indole-2-carboxylic acid (I2CA). We combine density functional theory gas-phase (DFT) calculations with scanning tunneling microscopy to reveal details of I2CA assembly in two different solvents at the solution/solid interface, and on Au(...
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A straightforward synthesis of indole-2-carboxylic esters was developed through a ligand-free copper-catalysed condensation/coupling/deformylation cascade process from 2-halo aryl aldehydes or ketones with ethyl isocyanoacetate. The reactions proceeded well for most of the 2-iodo-, bromo-, and chloro-substrates under room temperature or mild conditions.
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ژورنال
عنوان ژورنال: Molbank
سال: 2020
ISSN: 1422-8599
DOI: 10.3390/m1145